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Appendix 4. Solubility table of acids, bases, and salts in water

Lecture



Solubility of acids, bases, and salts in water

Solubility is the ability of a substance to dissolve in water, forming a homogeneous solution.

  • If a substance is soluble, it dissociates completely (or almost completely) into ions and does not form a precipitate.

  • If a substance is slightly soluble, it dissolves poorly and may form a precipitate.

  • If a substance is insoluble, it practically does not dissolve — almost all of it remains as a precipitate.

Acids, bases, and salts

  • Acids — substances that yield H⁺ ions in solution. Example: HCl, H₂SO₄.

  • Bases — substances that yield OH⁻ ions in solution. Example: NaOH, Ca(OH)₂.

  • Salts — compounds of metals with acid residues. Example: NaCl, BaSO₄.

Appendix 4. Solubility table of acids, bases, and salts in water

How to use the solubility table?

The solubility table shows whether particular salts and bases are soluble in water. It is usually presented as a large grid, with cations (positive ions) listed by row and anions (negative ions) listed by column. At the intersection is indicated:

  • Р — soluble (forms a solution)

  • М — slightly soluble (a precipitate partially forms)

  • Н — insoluble (a precipitate forms)

  • — or blank — the compound does not exist or is not formed

Example: how to find out whether BaSO₄ is soluble?

  1. Find the cation Ba²⁺ along the vertical (row).

  2. Find the anion SO₄²⁻ along the horizontal (column).

  3. At the intersection there will be, for example, Н — meaning BaSO₄ is insoluble and forms a precipitate.

Example 2: Na₂CO₃ (sodium carbonate)

  1. Cation: Na⁺

  2. Anion: CO₃²⁻

  3. At the intersection — Р
    This means Na₂CO₃ is soluble in water.

Why is the table needed in chemistry?

  • To predict whether a precipitate will form in a reaction (for example, in an exchange reaction).

  • To understand the properties of substances — soluble substances more often participate in ionic equations.

  • To check the correctness of reactions — if a substance is insoluble, it remains as a precipitate rather than dissolving.

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