You get a bonus - 1 coin for daily activity. Now you have 1 coin

Flavoring Additives: Spices and Seasonings in Food Chemistry

Lecture



Flavoring additives for food, as well as condiments, spices, and seasonings, formerly known as flavoring substances — chemical substances, individual parts of biological products of plant origin, and their mixtures, intended to improve the taste and aromatic qualities of the food being prepared and of finished dishes.

Flavoring additives can help improve the digestion and absorption of food, as well as make it possible to store it for a long time. Flavoring additives include spices, salt, sugar, some flavorings, sauces, ready-to-eat products (ketchup, mustard, horseradish), butter blends (butter with mustard, herb butter, anchovy butter, crayfish butter, and the like), and other substances that affect taste or aroma (monosodium glutamate, acetic essence diluted with water, citric acid, and the like).

The term «condiment» in English (Condiment) comes from the Latin condimentum, meaning «spice, seasoning, sauce», and from the Latin condire, meaning «to preserve, to pickle, to season». Originally, this term described pickled or preserved foods, but its meaning changed over time.

General information

Flavoring Additives: Spices and Seasonings in Food Chemistry

A fish dish seasoned with various spices.

Flavoring additives can be natural products and synthetic substances. Natural products are used both fresh (fruits, seeds, stems, rhizomes) and dried, ground into powder; butter blends are also used, which not only improve the taste of a dish but also increase its caloric content.

Some flavoring additives are standardized; in this case, they can be included in a special category — food additives.

Among the most popular food additives are spices — fresh or dried parts of aromatic spice plants, containing pungent (spicy) and various volatile aromatic substances, predominantly of tropical origin. For the most part, these products have no nutritional value, but when added to food in small amounts, they give the prepared dish a distinctive taste and aroma. Various parts of plants are used as spices, for example: fruits (black pepper), flower buds (cloves), leaves (bay leaf), roots (parsley), rhizomes (ginger), bulbs (onion, garlic), and others.

Many spices reached Europe as far back as ancient times from the East (India and China); some — from Africa and South America.

History

Condiments were known in historical Ancient Rome, India, Greece, and China. There is a myth that, before the widespread adoption of food preservation methods, hot spices and condiments were used to improve the taste of food, but this claim is not supported by any evidence or historical records. The Romans made the condiments garum and liquamen, similar and sometimes synonymous preparations, by crushing the entrails of various fish and then fermenting them in salt, which resulted in a liquid containing glutamic acid, suitable for enhancing the taste of food. The popularity of these sauces led to a flourishing condiment industry. In «Apicius», a cookbook based on the cuisine of the 4th and 5th centuries, there is a section devoted exclusively to condiments

Preparation of single-component condiments and production of blends

  • Used as condiments are fresh or dried chopped aboveground parts of plants — dill, coriander; seeds — anise, poppy, mustard; fruits and seeds — black pepper, vanilla, star anise; flowers or their parts — capers, cloves; leaves — bay leaf; bark — cinnamon; rhizomes — ginger; bulbs — onion, garlic.
  • Condiments also include complex multi-component compositions, whether dry, paste-like, or liquid. Many peoples have their own traditional condiments: table mustard, soy sauce, khmeli-suneli, tkemali, mayonnaise, adjika, and other products.

Chemical composition

Flavoring Additives: Spices and Seasonings in Food Chemistry

A type of flavored sugar.

Many condiments and spices contain flavoring and aromatic substances — essential oils, often — glycosides, their accompanying sugars, starch, and tannins. Among the substances that determine the characteristic properties of spices are glycosides, terpenoids, simple and complex esters, as well as some carotenoids and organic sulfides (for example, diallyl disulfide).

Micronutrients

Condiments can benefit health. Micronutrient deficiency is widespread in Asia. To combat nutrient deficiency, certain condiments are added to food. Common condiments that help with micronutrient deficiency include fish sauce, soy sauce, spices, and bouillon cubes. Studies conducted in nine different Asian countries show that iodine and iron are common micronutrients whose deficiency is observed in many diets. The use of iodized salt can increase iodine intake by 9-80% of the recommended daily allowance (RDA). Adding bouillon cubes can increase iron intake by 3-40% of the RDA.

Classification of food additives

Condiments and food additives can be classified by origin (plant, mineral, synthetic), by purpose (flavorings, flavor enhancers, preservatives), as well as by form of use (dry, liquid, blends). Spices and seasonings are usually singled out as a separate group of plant additives, and condiments — as ready-made blends or sauces

Main groups

  • Spices: parts of plants (seeds, roots, bark, fruits) used for taste and aroma. Examples: pepper, cloves, cinnamon.

  • Seasonings: leaves and green parts of plants, more often fresh or dried. Examples: basil, dill, parsley.

  • Flavorings: substances that enhance smell and taste, which can be natural (vanilla, citrus oils) or synthetic.

  • Condiments: ready-made blends or products that accompany dishes (sauces, marinades, ketchup, mustard).

Classification by origin

  • Plant: spices, seasonings, essential oils.

  • Mineral: salt, baking soda.

  • Chemical/synthetic: monosodium glutamate, artificial flavorings, colorants.

By purpose in cooking

  • Flavor enhancers: monosodium glutamate, yeast extract.

  • Preservatives: vinegar, citric acid, potassium sorbate.

  • Colorants: turmeric, paprika, carmine.

  • Blends: curry, khmeli-suneli, Vegeta.

Comparative table of food additives

Category Examples Features
Spices Pepper, cinnamon, cloves Used in small doses, concentrated flavor
Seasonings Basil, parsley, dill Fresh or dried leaves, mild aroma
Flavorings Vanilla, citrus oils Enhance smell, can be natural and synthetic
Condiments Sauces, ketchup, mustard Ready-made products, often contain a blend of spices
Mineral additives Salt, baking soda Not of plant origin
Synthetic additives Monosodium glutamate, colorants Produced industrially, regulated by standards

The gustatory sensory system — a sensory system by means of which taste stimuli are perceived.

Taste receptors, like olfactory receptors, are chemoreceptors and are intended for monitoring the chemical composition of the environment. For example, in humans the consequences of the TAS2R reaction to the bitterness of coffee are different in the mouth and in the stomach. A vivid example of the importance of the site of interaction is histamine.

Taste is usually regarded as a contact sense (compare with sensation): the acting molecules are in a solution that comes into contact with the receptor, whereas smell, on the contrary, — is a distant sense, and the molecules of chemical substances are delivered to the receptors by air currents. Such a classification is very conditional both at the cellular and at the molecular level (the receptor mechanism in the case of both taste and smell may be one and the same). It is even more difficult to draw a boundary between taste and smell for aquatic animals, where the stimulating substances are always dissolved, as well as for a number of invertebrates (flatworms and annelids, mollusks). This article examines in detail the taste sensory systems proper of insects and mammals. Traditionally it was believed that sweet and salty tastes are perceived predominantly by the tip of the tongue, sour — by its sides, bitter — by the middle part of the back of the tongue. Nevertheless, the molecular and functional data available at present show that all taste receptors are distributed over the entire surface of the tongue and differ only in the density of their distribution. Thus, no «tongue map» exists, contrary to erroneous popular notions.

Classification of flavoring additives by taste groups

  • Hot: chili pepper, black pepper, mustard, ginger. Impart pungency, stimulate the appetite.

  • Aromatic-spicy: coriander, caraway, cardamom, cloves. Have a complex aroma, create a characteristic «warm» taste.

  • Aromatic herbal: basil, oregano, dill, parsley. Fresh, mild, green flavor notes.

  • Sweetish: cinnamon, vanilla, star anise, nutmeg. Add sweetness and mildness, often used in desserts.

  • Sour: citric acid, vinegar, sumac. Impart a refreshing, sour note.

  • Salty: salt, soy sauce. The basic taste that enhances the perception of others.

  • Bitterish: turmeric, fenugreek, horseradish. Add depth and balance, often in small doses.

  • Umami (meaty, rich taste): monosodium glutamate, soy sauce, mushrooms, seaweed. Creates a «hearty», rich taste.

Flavoring Additives: Spices and Seasonings in Food Chemistry

Table of classification by taste

Taste group Examples Features
Hot Chili pepper, ginger Pungency, warming effect
Spicy Cardamom, cloves Complex aroma, warmth
Aromatic herbal Basil, dill Freshness, green taste
Sweetish Cinnamon, vanilla Mildness, dessert notes
Sour Vinegar, sumac Refreshing, sour taste
Salty Salt, soy sauce Enhancement of other tastes
Bitterish Turmeric, fenugreek Balance, depth
Umami Soy sauce, mushrooms Richness, meaty note
An interesting point: many spices fall into several categories at once. For example, ginger — is hot but also slightly sweetish; soy sauce — is salty and umami.

Application

Condiments are used in cooking, the food industry (canning, confectionery, baking, distilling), as well as in medicine and perfumery.

At present, in industry, instead of condiments in the form of fresh and dried parts of plants, prepared products are often used — powders, pastes, extracts, essential oils, as well as synthetic and semi-synthetic flavorings.

Physiological role

The main role of condiments — is to enhance the taste qualities of food, improve its aroma, stimulate the appetite, and sometimes — to mask undesirable organoleptic properties of products.

In addition to imparting new taste and aromatic qualities to food, some condiments can serve as a source of organic acids (vinegar), enzymes (soy sauce), and, to some extent — of trace elements — iron, calcium, iodine, etc.

Common seasonings, spices, condiments

Mineral

  • Salt (a spice).

Plant-based

Flavoring Additives: Spices and Seasonings in Food Chemistry

Anise

Flavoring Additives: Spices and Seasonings in Food Chemistry

Peppermint

Flavoring Additives: Spices and Seasonings in Food Chemistry

Fresh ginger root

Flavoring Additives: Spices and Seasonings in Food Chemistry

Nutmeg

Flavoring Additives: Spices and Seasonings in Food Chemistry

Rosemary

Flavoring Additives: Spices and Seasonings in Food Chemistry

Horseradish

  • Sweet flag — the dried rhizomes are used as a spice;
  • Quince — the fruits;
  • Ajwain (bishop's weed) — the seeds;
  • Anise — the seeds (whole or ground);
  • Orange — the juice, the zest (the zest — is the outer layer of the peel);
  • Asafoetida — the milky sap of the roots;
  • Star anise — the dry ripe fruits (whole or ground);
  • Basil (raihon, reyhan) — the green parts of the plant (fresh or dried and ground);
  • Barberry — the berries (fresh, pickled, or dried and ground);
  • Valerian — the fresh leaves;
  • Vanilla — natural in pods;
  • Galangal (galanga) — the rhizome;
  • Cloves — the dried flower buds;
  • Mushrooms — dried (whole and ground);
  • Mustard — the fresh leaves, seeds, powder, paste;;
  • Oregano — the leaves (fresh or dried and ground)
  • Sweet clover — the leaves and stems;
  • Zira (Cumin) — the seeds (whole or ground);
  • Ginger — the rhizome (fresh, dried, powder);
  • Hyssop — the young leaves (fresh or dried and ground);
  • Nigella, or black cumin — the seeds are used;
  • Camphor tree (Cinnamomum camphora) — Culinary camphor is obtained by distilling the aromatic leaves and wood of the tree; it consists of crystals outwardly resembling large crystals of salt;
  • Cardamom — the shelled seeds (whole and ground);
  • Chervil — the young leaves;;
  • Cumin — the young shoots and leaves
  • Coriander (the greens — cilantro, kashnish) — the greens (fresh, freshly frozen, or dry), the seeds (dried);
  • Cinnamon — the dried bark (whole or ground);
  • Red pepper — the fruits (fresh or dried and ground);
    • Chili pepper — the fruits (fresh or dried and ground);
    • Allspice — the fruits (fresh or dried and ground);
  • Garden cress (cress) — the greens;
  • Sesame — the seeds;
  • Turmeric — the roots, powder;
  • Laurel — the bay leaf (dried), powder;
  • Licorice (liquorice) — the rhizome;
  • Lemon — the zest and juice;
  • Alliums:
    • Bulb onion — the whole plant;
    • Leek — the white stem, (young leek bulbs);
    • Shallot — the young leaves and bulbs;
    • Welsh onion (bunching onion, Tatar onion) — the whole plant or the young leaves;
    • Victory onion — the young shoots and bulbs;
    • Chives — the leaves, bulbs, and flowers;
    • Ramson (bear's garlic, kalba) — the stem, leaves, and bulb;
  • Lovage — the whole plant (fresh or dry);
  • Marjoram — the leaves;
  • Poppy — the seeds;
  • Lemon balm (melissa) — the leaves (fresh or dried and ground);
  • Juniper — the berries (fresh or dried and ground);
  • Nutmeg — the seed of the fruits;
  • Mint — the leaves;
  • Nasturtium — the young leaves, flowers;
  • Borage — the fresh young leaves;
  • Olives — the fruits (salted or pickled);
  • German madwort (asperugo) — the young leaves;
  • Fenugreek (shambhala) — the seeds, leaves, and tender stems;
  • Blue fenugreek (Utskho-suneli) — the fruits and inflorescences, dried powder;
  • Paprika — the fruits;
  • Parsnip (field borscht) — the seeds, shoots;
  • Black pepper — whole peppercorns or ground;
  • Turgenia — the leaves and fruits;
  • Parsley — the leaves and roots;
  • Wormwood — the young apical leaves (dried);
  • Purslane — the young shoots and leaves, collected before flowering;
  • Rhubarb — the leaves and stalks;
  • Rosemary — the young leaves;
  • Arugula (rocket, eruca) — the young shoots and leaves;
  • Sarsaparilla — the young apical shoots;
  • Celery — the stalks (fresh), the leaves (fresh, frozen, and dry), the root (fresh, frozen, and dry)
  • Shiso, or perilla. An oilseed plant used as a condiment in Korea;
  • Sumac — the fruits, the skin of the fruits;
  • Thyme — the upper part of the stem with leaves;
  • Caraway — the seeds;
  • Tomatoes — a paste made from the fruits;
  • Yarrow — the leaves and inflorescences, also in dried ground form;
  • Dill — the ground shoots, flowers, seeds;
  • Fennel (sweet fennel) — the young leaves, seeds;
  • Horseradish — the root, leaves;
    • Wasabi — the rhizome;
  • Cydonia — the fruits of the quince;
  • Savory (jambul, citron) — the leaves;
  • Thyme — the upper part of the stem;
  • Garlic — the whole plant;
  • Woundwort — the inflorescences and leaves;
  • Sage — the leaves;
  • Saffron — the flower stigmas;
  • Tarragon (estragon) (tarragon wormwood) — the young plants or leaves (fresh and dried); the leaves are used for preparing tasty boiled meat and beverages.

Obtained by artificial and synthetic means (spices)

  • Vanillin and ethylvanillin — a crystalline powder
  • Monosodium glutamate — a crystalline powder
  • Citric acid — powder and liquid
  • Sugar — a crystalline powder or icing sugar
  • Vinegar — a liquid
  • Fructose — powder

Blends

  • Adjika — a ground hot paste-like blend.
  • Vegeta — a blend of dried vegetables, spices, salt, sugar, and flavor enhancers (monosodium glutamate).
  • Curry — a blend of dry spices in powder form
  • Masala
    • Garam masala
  • Svan salt
  • Khmeli-suneli — a ground hot blend of spices and condiments of a green or olive color

Standardized concentrates of condiments and spices

Flavoring Additives: Spices and Seasonings in Food Chemistry

Spice extracts.

At present, proprietary spice concentrates obtained by extraction, including supercritical extraction using alcohol, freon, carbon dioxide, and other solvents as extractants, are widespread. The use of carbon dioxide as a solvent (the CO2-extraction method) is the most preferable method of extraction, because it preserves thermolabile compounds, such as, for example, vitamins.

Standardized condiment concentrates usually have a liquid or oily form. Most of them are lipophilic (soluble in oil and insoluble in water), but there also exist water-soluble concentrates, created in the form of emulsions.

Advantages of using concentrated condiments in cooking:

  • Improved logistics: liquid condiments — are uniform liquid ingredients with the same principles of use; there is no need to take into account the mode of use specific to each of them.
  • Compared with ordinary condiments, the taste and smell of liquid condiments in a dish is released instantly and spreads quickly and evenly throughout the entire volume of the dish.
  • The possibility of use in cold dishes, in which ordinary spices do not release their flavor.
  • They improve the organoleptic characteristics of a dish thanks to the absence of ballast plant impurities that have given their flavor to the finished product and are no longer needed in it.
  • They are more convenient to store than ordinary spices: they do not spill, do not lose their aroma, do not become moldy, and do not dry out. Throughout the entire shelf life the characteristics are stable and uniform.
  • Increased convenience of use and dosing compared with ordinary spices: ingredients that are identical in their characteristics, in uniform packaging with uniform conditions of use, which can simply be taken from the shelf and added to the dish being prepared.

Hot condiments

Hot condiments can be beneficial when consumed in moderation — they speed up the metabolism, improve digestion, and have antibacterial properties. However, an excessive amount can cause stomach irritation, heartburn, and aggravate chronic gastrointestinal diseases.

Benefits of hot condiments
  • Acceleration of the metabolism Capsaicin (a substance in chili pepper) stimulates thermogenesis, which helps to burn calories faster and may contribute to weight loss.

  • Antibacterial properties Pepper, garlic, ginger, and turmeric suppress the growth of bacteria, which historically helped to preserve food in hot climates.

  • Improvement of digestion Hot spices stimulate the production of gastric juice and enzymes, facilitating the digestion of food.

  • Energy and mood Capsaicin stimulates the production of endorphins, which improves mood and reduces stress.

  • Prevention of colds Ginger and garlic have anti-inflammatory and immunomodulatory effects.

Harm and limitations of hot condiments
  • Irritation of the mucous membrane With gastritis, ulcers, or reflux, hot spices can increase pain and heartburn.

  • Increased blood pressure In people with hypertension, excessive consumption can provoke spikes in blood pressure.

  • Risk of habituation Constant consumption of very hot dishes reduces the sensitivity of the receptors, and a person begins to add more and more spices.

  • Sleep disturbance Hot food in the evening can cause insomnia due to stimulation of the nervous system.

  • Fast food with hot sauces It is not so much the pepper that is harmful, as the fatty and salty additives (ketchups, mayonnaises, ready-made sauces).

Comparative table of hot condiments
Condiment Benefit Possible harm
Chili Speeds up metabolism, antibacterial Heartburn, gastrointestinal irritation
Ginger Improves digestion, anti-inflammatory May cause allergy
Garlic Antibacterial, strengthens immunity Irritates the stomach with gastritis
Turmeric Reduces inflammation, antioxidant In large doses — nausea
Horseradish/wasabi Stimulates circulation, clears the nose May cause watering eyes, irritation of the mucous membrane
Mustard

Stimulates enzymes, improves appetite,

contains antioxidants, vitamins, minerals

Lowers cholesterol, supports the heart

Mustard plasters for colds, improves the skin

Detoxification, anti-inflammatory action

Aggravates gastritis, ulcers,

Allergy is possible

May raise blood pressure

Risk of burns with external use

With overuse — irritation of the mucous membrane

When is it best to consume hot condiments?

  • Beneficial: in the morning or during the day in moderate amounts, as part of a complete dish.

  • Harmful: on an empty stomach, late in the evening, with chronic gastrointestinal diseases, or in combination with fatty/salty food.

Ways of enhancing and weakening tastes with various substances and cooking methods

Taste can be enhanced with the help of salt, acids (lemon, vinegar), spices, and proper heat treatment; weakened — by dilution, the addition of fats, starch, or heat treatment, which smooths out bright notes.

Main ways of enhancing the taste of food

  • Salt: enhances the perception of sweetness and suppresses bitterness.

  • Acids (lemon juice, vinegar, tomatoes): refresh the taste, neutralize fattiness.

  • Spices and herbs: add new aromatic notes, enhance the basic tastes.

  • Sugar and sweet components: balance acidity and bitterness.

  • The addition of fat (liquid or by mixing with a solid) enhances existing tastes

  • Umami enhancers (monosodium glutamate, mushrooms, soy sauce): make the taste richer.

  • Serving temperature: hot dishes release aromas 40% better than cold ones.

  • Heat treatment (frying, baking): caramelization and Maillard reactions enhance the taste.

Ways of weakening the taste of food

  • Dilution with liquid: water, broth, or milk reduce the concentration of tastes.

  • The addition of fats (cream, butter): soften pungency and acidity.

  • Starchy products (potatoes, rice): absorb excess salt or acid.

  • Prolonged boiling: makes the taste milder, but may deprive the dish of vividness.

  • Sugar: weakens the perception of acidity and bitterness.

  • Cooling: cold dishes seem less aromatic and less rich.

Comparative table of enhancing and weakening the taste of food

Method Taste enhancement Taste weakening
Salt Emphasizes sweetness, suppresses bitterness In excess, may mask other aromas
Acids Refresh, balance fattiness In large doses make the taste sharp, require softening
Spices Add depth and complexity When overloaded, may overpower the main taste
Fats Enhancement of texture, «body» of taste Softening of pungency and acidity
Temperature Hot enhances the aroma Cold reduces perception
Starch No Absorbs excess salt/acid

Features

  • Balance is more important than quantity: too much salt or spices does not enhance the taste but destroys the harmony.

  • Combinations work better: acid + salt + spices give a multi-layered taste.

  • Cooking methods affect perception: frying enhances, boiling softens, stewing balances.

The basic tastes and their chemical nature

  • Sweet: caused by sugars (for example, sucrose), some alcohols, and artificial sweeteners. The molecules must have a certain spatial structure and solubility in order to activate the receptors.

  • Sour: associated with the presence of acids (for example, citric, acetic), where hydrogen ions (H+) stimulate the receptors.

  • Salty: determined mainly by sodium chloride (NaCl), as well as by other salts of alkali metals.

  • Bitter: caused by glycosides (for example, amygdalin) and alkaloids (caffeine, quinine). Bitterness often signals potentially toxic substances.

  • Umami: a taste discovered later, associated with monosodium glutamate and nucleotides. It enhances the sensation of a «meaty» or «broth-like» taste.

  • special tastes are distinguished — the taste of nuts, the taste of water, umami, astringent, pungent, minty, alkaline, metallic — therefore these substances are often added to food.

Flavoring Additives: Spices and Seasonings in Food Chemistry

The mechanism of taste perception

  • Taste molecules are called glucophores — they have low volatility, are soluble in water, and have a specific shape for binding with receptors.

  • Chemoreception — the process by which food molecules interact with protein receptors on the tongue.

  • Different areas of the tongue are sensitive to different tastes, but modern science clarifies that the receptors are distributed more evenly than was previously thought.

  • Combinations of tastes create complex profiles (for example, the sweet-sour taste of fruits).

  • Food additives often enhance or mask tastes, affecting the perception of the product.

  • Evolutionary role: sweet signals energy, salty — minerals, sour and bitter — possible danger, umami — proteins.

Flavoring Additives: Spices and Seasonings in Food Chemistry

The diagram above depicts the signal transduction pathway of the sweet taste. Object A — is a taste bud, object B — is a single taste cell of the taste bud, and object C — is a neuron attached to the taste cell. I. Part I shows the reception of the molecule. 1. Sugar, the first messenger, binds to a protein receptor on the cell membrane. II. Part II shows the signal transmission by transmitter molecules. 2. G-protein receptors, secondary messengers, are activated. 3. The G-proteins activate adenylate cyclase, an enzyme that increases the concentration of cAMP. Depolarization occurs. 4. The energy from step 3 is used to activate K+, potassium, protein channels. III. Part III shows the response of the taste cell. 5. Ca+, calcium, protein channels are activated. 6. The increased concentration of Ca+ activates the neurotransmitter vesicles. 7. The neuron connected to the taste bud is stimulated by neurotransmitters.

Flavoring Additives: Spices and Seasonings in Food Chemistry

The diagram depicts the signal transduction pathway of the sour or salty taste. Object A — is a taste bud, object B — is a taste receptor cell inside object A, and object C — is a neuron attached to object B. Part I — is the reception of hydrogen ions or sodium ions. 1. If the taste is sour, H + ions from acidic substances pass through H + channels. Depolarization occurs. II. Part II — is the signal transduction pathway through transmitter molecules. 2. Channels for cations, such as K +, open. III. Part III — is the response of the cell. 3. The influx of Ca + ions is activated. 4. Ca + activates the neurotransmitters. 5. A signal is sent to the neuron attached to the taste bud.

Flavoring Additives: Spices and Seasonings in Food Chemistry

The diagram above shows the signal transduction pathway of the bitter taste. The bitter taste has many different receptors and signal transduction pathways. Object A — is a taste bud, object B — is a taste cell, and object C — is a neuron attached to object B. Part I — is the reception of the molecule. 1. A bitter substance, such as quinine, is consumed and binds to receptors coupled to G-proteins. II. Part II — is the signal transduction pathway. 2. Gustducin, the secondary messenger of the G-protein, is activated. 3. Then phosphodiesterase, an enzyme, is activated. 4. A cyclic nucleotide, cNMP, is used, reducing the concentration. 5. Channels, such as potassium channels (K+), close. III. Part III — is the response of the taste cell. 6. This leads to an increase in the level of Ca+. 7. The neurotransmitters are activated. 8. The signal is transmitted to the neuron.

Comparative table of tastes

Taste Main compounds Examples of products Function in nutrition
Sweet Sugars, polyols, sweeteners Fruits, honey, candy Energy signal
Sour Organic acids Lemon, sauerkraut Acidity regulation
Salty NaCl, KCl Salt, seafood Mineral balance
Bitter Alkaloids, glycosides Coffee, cocoa, wormwood Protective signal
Umami Glutamate, nucleotides Meat, soy sauce Enhancement of the taste of proteins
Mixing of tastes
The taste confusion matrix (TCM) — is a method in which many compounds are tested simultaneously. It is a study of human taste perception. It characterizes taste quality using the identification patterns of approximately 10 stimuli being analyzed.

Non-basic tastes and aftertastes

Starchy taste

The starchy taste was officially described quite recently (formerly it was believed that carbohydrates themselves could have only a sweet taste). Such a «starchy» taste is possessed by products that contain carbohydrates and polysaccharides. An experiment with a rat is described: it was given a choice between two vessels with liquid: in one there was just water, and in the other — water with a 0.5-percent starch solution. The rat chose the water solution with starch. A person rarely senses the taste of starch because of the addition of sugar.

Fatty taste

Fatty as a taste characteristic has been mentioned from time to time at least since the 1800s. Some researchers are not yet certain that this sensation is differentiated in all people and, citing the fact that the experiments were carried out on animals, are in no hurry to recognize this taste as «basic».

A person undoubtedly perceives a «fatty» taste — but this sensation is not as clearly expressed as the usually distinguished standard tetrad «sweet-sour-bitter-salty».

In some people with impaired liver function (for example, after hepatitis), the taste or sight of fatty food can cause unpleasant sensations.

Pungent taste

The pungent taste is not counted among the basic tastes, since no corresponding taste receptors have been discovered to date. It is associated with substances that stimulate the «heat» receptors — ethanol, capsaicin (the active substance of red pepper), piperine (the active substance of black pepper) — they excite branches of the trigeminal nerve and contribute to the «purely gustatory» sensation. The measure of pungency is the Scoville scale.

Flavoring Additives: Spices and Seasonings in Food Chemistry

Cooling taste

Some substances (for example, menthol) are able to act on the TRPM8 protein contained in the cold receptors. That is precisely why, when they come into contact with the tongue and the mucous membranes of the mouth, a sensation of a cooling taste arises.

Astringent taste

The astringent taste («puckering taste») is associated with the reception of tannins (tannins in tea, in blackthorn berries, etc.). The mechanism of its occurrence is attributed to the binding of tannins with proline-rich proteins. Sometimes this taste is not distinguished and is assessed as a variant of bitter.

Numbing taste

Both Chinese cuisine and Batak Toba cuisine include the idea of 麻 (má or mati rasa), the tingling numbness caused by such spices as Sichuan pepper. The cuisine of Sichuan province in China and of the Indonesian province of North Sumatra is often combined with chili pepper to produce the taste 麻辣 málà, «numbing and pungent» or «mati rasa». Typical of northern Brazilian cuisine is jambu — an herb that is used in dishes such as tacacá. These sensations, although not gustatory, fall into the category of chemesthesis.

Rich taste

Some Japanese researchers mention the taste kokumi (Japanese 濃味) from koku — rich, thick, and mi — taste, which is translated as «richness», «fullness of taste», or «richness», and describes chemical compounds in food that themselves have no taste of their own but enhance the taste characteristics when combined with other substances. Together with the five basic tastes — sweet, sour, salty, bitter, and umami — kokumi is described as something that can enhance the other five tastes, increasing and prolonging their perception, creating an effect of «fullness in the mouth». Garlic — is a common flavoring ingredient that helps to define the characteristic kokumi taste.

Metallic taste

A metallic taste is characteristic of fresh (uncoagulated) blood, and is also usually felt in food that has come into contact with oxidized metals (spoons, forks, cans). A particularly strong metallic taste is observed on contact with copper alloys — brass, cupronickel, etc., which is why tableware made of cupronickel and nickel silver is coated with a thin layer of silver.

This sensation can serve as a sign of certain diseases; poisoning by metals (for example, in metal fume fever), by pesticides or chemical warfare agents, the action of certain medicinal products, for example metronidazole, etc.

A metallic taste in the mouth also usually arises during an electrophoresis procedure.

Chalky taste

The characteristic taste of chalk has been identified as the calcium component of this substance. In 2008, geneticists discovered a calcium receptor on the tongue of mice. The CaSR receptor is normally located in the gastrointestinal tract, kidneys, and brain. Together with the «sweet» receptor T1R3, the CaSR receptor can detect the taste of calcium.

Taste disorders

Taste disorders can be in the form of:

  • quantitative sensation (of receptor, conduction, or central origin):
    • ageusia
    • hypogeusia
    • hypergeusia
  • qualitative sensation (dysgeusia):
    • parageusia
    • glycogeusia (a constant sensation of sweetness, may occur with diabetes mellitus)
    • taste hallucinations (may occur with temporal lobe epilepsy).

The names of the disorders are formed from the Greek word γεύσεις — tastes — and the corresponding prefixes.

Dysgeusia arises for various reasons — pregnancy, diabetes mellitus, diseases of the gastrointestinal tract or oral cavity, anemia, hypothyroidism, etc.

A distinction is made between ageusia — the loss of one of the basic taste sensations, hypogeusia — the weakening of one of the sensations, parageusia, when salty is sensed instead of sweet, and taste hallucinations (when the sensation of one or another taste is observed without obvious physical causes, for example, with neuroses).

A sensation of taste can arise under the action of radioactive irradiation, in some cases at levels of about 1 R/h.

Loss of taste and smell are among the characteristic symptoms of COVID-19 due to the coronavirus damaging the olfactory epithelium.

An impairment of taste perception can also be physiological, for example in the absence of nasal breathing (pinching the nostrils), or under the action of certain substances, for example ziziphin or gymnemic acid, contained in the leaves of the true jujube and of forest gymnema (Apocynaceae), whereupon a loss of sensitivity to sweet, bitter, and pungent is observed, while sensitivity to sour and salty is preserved.

An impairment of taste perception in cooks is called bridost (palate fatigue).

History of the development of the theory of taste

The concept of «basic tastes» dates back at least to the times of Aristotle. In European cultures, 4 «basic tastes» were traditionally distinguished. Aristotle mentioned «sweet» and «bitter» as basic, and «meaty taste», «salty», «pungent», «astringent», «puckering», and «sour» — as having developed from these two «basic» ones. In Dahl's work, sayings are given that testify to a linguistic conflation of the concepts «bitter», «astringent», and «sour» in the 19th century.

In the terminology of professional tasters (of food products, tea, coffee, wine, tobacco), the number of basic tastes used is substantially greater, but these terms relate rather to aroma than to taste proper. Researchers from the University of Oregon proposed including a «sixth taste», starchy, in the classification. In November 2005, French researchers showed that rats also distinguish a «fatty» taste.

In ancient Chinese philosophy of the five elements, five basic tastes were described: bitter, salty, sour, sweet, and pungent.

However, in the East 6 tastes have long been distinguished, including «pungent» (pepper, radish, mustard) and «bitter» (cinchona, bitter melon).

In 1908, the Japanese chemist Kikunae Ikeda gave a name to the taste umami, which he originally recognized in kombu seaweed, and also isolated from the seaweed monosodium glutamate, which possesses this taste. In 1985, the concept of «umami» was officially recognized as a scientific term at the First International Symposium on Umami (Hawaii).

The concept of «taste» in culture

The expression «There is no arguing about tastes (and colors)» (variant: «There are no comrades when it comes to taste and color», jocular: «When it comes to taste and color, all markers are different»), known in many languages, illustrates people's vague understanding of descriptions of taste, differences in the assessment of positivity in sensory perception among different people and ethnic groups, and the pointlessness of their absolute reconciliation.

See also

  • Dip – a type of condiment
  • Garnish – a decorative element added to food or drink.
  • List of brand-name condiments
  • List of condiments
  • List of fish sauces
  • List of foods
  • List of mustard brands
  • Uncooked seasoning – a substitute for malt vinegar
  • Seasoning – the process of enriching food with herbs, salt, or spices.
  • Herbaceous plant – a plant used for food, medicine, or the production of perfumery.
  • Spice – a food flavoring
  • Relish – cooked, pickled, or chopped vegetables or fruits used as a condiment.
  • Pickling – the procedure of preserving foods in brine or vinegar
  • Beef meat peptide
  • Digital lollipop
  • Gustatory nucleus
  • Optimal foraging theory
  • Palatability
  • Mouthfeel
  • Neurogastronomy
  • Vomeronasal organ
  • Sensory analysis
  • Tea tasting
  • Wine tasting

Comments

To leave a comment

If you have any suggestion, idea, thanks or comment, feel free to write. We really value feedback and are glad to hear your opinion.
To reply

Lectures and tutorial on "Пищевая химия"

Terms: Пищевая химия